Do you beleive these stats on Battery Voltages? - Page 4

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Posted by ralleyrat on January 16, 2010, 2:01 am
 
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On Nov 28 2009, 12:52 pm, âÍÁ Á³Õ »Ñ·àÁ ËØÁ <=
macmi...@gmail.com>
wrote:

Manufactueres would not disagree.
It's called 'surface charge' and 'pros' will lightly load a battery
for a minute or so to
drain it before they take voltage to estimate the 'state of charge' to
which you refer.

Posted by paul c on November 28, 2009, 1:12 pm
 

Bob wrote:

Is the first part a quote?  If so I'd like to know where it came from.

Some of the sentences are a bit murky to me, eg., 'healthy battery
implies 12.2 to 12.8 V'.  It's logically patent that you can't conclude
'12.6 V implies good battery' from that but the last sentence about
voltage being a 'poor guide' gibes with experience.

Even though there are grade-school kids who know more about chemistry
and physics than I do, I find it helpful to remember that voltage is not
a consumable quantity, rather it's a ratio of energy to charge, eg.,
joules per coulomb.  So my no doubt over-simplified arithmetic tells me
that there are only so many coulombs in a battery.  Personally I find
this to be a more tangible quantity, ie. more useful than the usual
voltage metaphors such as water in pipes or waterfalls. I know they have
some water inside but otherwise I try to keep water away from batteries!

It seems that a low surface charge can drive a multimeter just as well
as a high charge, but when it comes to high current draws such as
electric starter motors, a lot depends on just how many coulombs one
needs to expend.   Even that doesn't encompass all the variables such as
the ratio of acid to water, plate thickness and quality and a bunch of
others I don't know much about that all affect internal resistance but
it helps to explain why I couldn't start a 1500 cc thumper with a 12.2 V
battery when the same battery could afterwards start a 50cc scoot.

On the other hand, I've been fooled more than once by a 12.8 V battery
that wouldn't start an engine until it was charged to 13.0 V, then
noticing some ground wire corrosion and after replacing that the same
battery now 'depleted' to 12.4 V started the engine immediately.  The
first time I made this mistake, I measured resistance of the ground wire
wire with a fairly high precision ohmmeter. This seemed an easier test
to do than voltage drop. I saw 0.24 ohms and thought that was pretty
darn low resistance and couldn't possibly be the problem.  But it seems
that the effective resistance of a starter motor in good condition is
much less than that.

Posted by Bob on November 28, 2009, 5:08 pm
 


|>Bob wrote:
|>> Battery Voltages
|>>     Because batteries are always referred to as 12-volt (or 6V or 24V),
|>> it is often assumed that the normal voltage is 12V. In fact a
|>> 12V lead-acid battery only producing 12.0V is either
|>> almost flat or is delivering a large current (under a heavy load).
|>> In fact, a healthy 12V battery, when not being charged,
|>> should always show 12.2 - 12.8V.
|>>
|>>     Very conveniently, the relationship between a battery's state
|>> of charge and its voltage is linear (10% per 0.10V) between about 90%
|>> (12.70V) and 20% (12.0V). However, when a battery has been on
|>> charge, even if its not fully charged, the voltage will be up
|>> around 13.8V. This will slowly drop to around 13.6V over the next
|>> few hours, but even if left overnight it shouldn't drop below
|>> 13.0V unless the battery was only partly charged or is on the way out.
|>>     But, as soon as a reasonable sized load is switched on, the voltage
|>> drops quite quickly until it equates to the battery's actual
|>> state of charge. Thereafter, the rate of voltage change (under
|>> constant load) becomes linear. Thus, in practice, the voltage
|>> of a freshly charged battery is a poor guide to its state of charge
|>> until some of the charge has been used.
|>>
|>> ==================================================
|>>
|>>     If the part about (will slowly drop to around 13.6V over the next
|>> few hours) is still true for small m/cycle batteries, and is not RC/Ah
|>> specific, then I've been getting ripped of on some of the "wet' sla GS/Yuasa
|>> batteries I've been buying..
|>>
|>>     I know, even the "agm" Chinese batts can hold these stats, but even
|>> 13.6 volt  "agm" is a drag to start, whereas  even a 12.6v "wet" will snap
|>> start better.
|>>
|>>     The Chinese "agms" seem more like a "gel" battery rather than a
|>> Starting Battery, I think an AGM with cell vent cap holes is pretty unreal
|>> and may just be a bunch of sponge mixed with a sulphuric acid solution,
|>> rather than a real AGM,which is much different...and Concorde pricier.
|>>
|>> Bob
|>
|>Is the first part a quote?  If so I'd like to know where it came from.
|>

A quote at:

Useful Info
       Very conveniently, the relationship between a battery's state of
       charge and its ... up around 13.8V. This will slowly drop to
       around 13.6V over the next few hours, .... Visit
       http://www.adverc.co.uk  or http://www.sterling-power.com  for ...
       www.attfield.dircon.co.uk/info-indx.html

|>Some of the sentences are a bit murky to me, eg., 'healthy battery
|>implies 12.2 to 12.8 V'.  It's logically patent that you can't conclude
|>'12.6 V implies good battery' from that but the last sentence about
|>voltage being a 'poor guide' gibes with experience.
|>
    That's reassuring, I was beginning to think I was getting ripped-off
all over on those readings...

|>It seems that a low surface charge can drive a multimeter just as well
|>as a high charge, but when it comes to high current draws such as
|>electric starter motors, a lot depends on just how many coulombs one
|>needs to expend.   Even that doesn't encompass all the variables such as
|>the ratio of acid to water, plate thickness and quality and a bunch of
|>others I don't know much about that all affect internal resistance but
|>it helps to explain why I couldn't start a 1500 cc thumper with a 12.2 V
|>battery when the same battery could afterwards start a 50cc scoot.
|>
    Surface charges are easily fixed with recharging or topping for a
longer time, to put a difference between Quick "surface" Charge, and a real
holding voltage..

|>On the other hand, I've been fooled more than once by a 12.8 V battery
|>that wouldn't start an engine until it was charged to 13.0 V, then
|>noticing some ground wire corrosion and after replacing that the same

    You mean like a "dirty" Neg(-) terminal right, or something like
that?...the Neg(-) terminal goes to the rectifier right?, which holds some
up to 14.9v no load voltage, but allows you to desulfate/egualise charge at
16v/2Ah through it.....
    I don't really understand the Rectifier's 14.0-->14.9v no
load/22A/withstand 200volt meaning.....what is NO LOAD and why does the
rectifier allow 16volts/2ah then.

    I can't figure that, when I do that, I ground on the frame/terminal,
and no main fuse blow...lucky maybe? If I turn the ignition on even at a 2Ah
setting I'm sure to blow the 40amp main fuse for sure.

Bob


Posted by paul c on November 28, 2009, 6:46 pm
 

Bob wrote:
...

I meant a copper ground wire where all the strands had turned green.

As for de-sulphating, I was taught that you need a constant-current
charger, and even then it's not always possible.  The documentation for
the small Ctek charger I use specifically says that it switches
periodically from constant-voltage to constant-current mode.  I'm pretty
sure it has succeeded on three different batteries but once it took
about a week.  All of those batteries were MF Yuasa's, which I believe
is a fairly high-quality brand.  One of them was three years old and had
sat in a neighbour's unused bike outside from October to June so it
never got very warm.  On the other hand, it couldn't save a one-year old
cheap refillable import battery that sat unused just over the winter
months, even with two weeks on that de-sulphating charger.  Maybe a more
expensive constant-current charger that can give larger currents for
short periods would have worked, I don't know.  Or maybe the guy I got
the battery from had filled it with tap water that was full of various
metals. Around here there is a lot of iron in the water.






Posted by Brian Gaff on November 29, 2009, 7:05 am
 

Well, look at psus for powering car equipment, its normally a nominal 13.8v.
Also of course all cells are not equal, and  some may drop a little more
than others.

Its not just lead acid though, its all batteries and a lot of the
performance has to depend on the electrode area.
Brian

--
Brian Gaff - briang1@blueyonder.co.uk
Note:- In order to reduce spam, any email without 'Brian Gaff'
in the display name may be lost.
Blind user, so no pictures please!


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